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Chemical etching: a key step to optimize the surface properties of PET film to improve the adhesion of the metallization layer

Jun 20,2024

In the production process of metallized PET film, the surface properties have a decisive influence on the adhesion and uniformity of the metallization layer. Therefore, it is particularly important to properly pretreat the surface of the PET film. Among the many pretreatment technologies, chemical etching has attracted much attention due to its unique effects and broad application prospects.

Chemical etching is a method of changing the surface properties of a material through a chemical reaction. In the production process of PET film, chemical etching is mainly used to remove unfavorable factors such as oxide layers and impurities on the surface of the film, thereby improving its surface state and creating ideal conditions for subsequent metallization steps.

In the chemical etching process, we use specific chemical reagents to etch the surface of the PET film. These chemical reagents usually have strong oxidizing or reducing properties, and can react chemically with pollutants and oxide layers on the surface of the film to generate substances that are easily soluble in water. As the reaction proceeds, the pollutants and oxide layers are gradually dissolved and peeled off, making the surface of the PET film gradually clean and smooth.

The mechanism of chemical etching treatment is mainly reflected in the following aspects:
Removing pollutants: Chemical etching treatment can effectively remove pollutants such as oil and dust on the surface of PET film, reducing the adverse effects of these pollutants on the adhesion of the metallized layer.
Removing oxide layer: PET film may form an oxide layer during the production process, which will affect the adhesion and uniformity of the metallized layer. Chemical etching treatment can dissolve and peel off the oxide layer and restore the original state of the film surface.
Improving surface roughness: Chemical etching treatment can improve the roughness of the surface of PET film to a certain extent, making it more uniform and smooth. This surface state is conducive to the uniform adhesion and close bonding of the metallized layer.
Increasing surface energy: After chemical etching treatment, the surface energy of PET film will change, making it easier to combine with the metal layer. This change helps to improve the adhesion and stability of the metallized layer.

After chemical etching treatment, the surface of PET film will become smoother, cleaner, and have a certain roughness and surface energy. These changes will directly affect the adhesion of the metallized layer. Specifically, a clean surface can reduce the contamination and obstruction of metal atoms during the deposition process; appropriate roughness can provide more attachment points; and increased surface energy can enhance the interaction between the metal layer and the PET film. Therefore, the PET film treated with chemical etching will have better adhesion and uniformity of the metallization layer.

Chemical etching is a key step to optimize the surface properties of PET film and improve the adhesion of the metallization layer. By removing pollutants and oxide layers, improving surface roughness and increasing surface energy, chemical etching can significantly improve the surface state of PET film and create ideal conditions for subsequent metallization steps. Therefore, in the production process of metallized PET film, we should pay attention to and make full use of the advantages of chemical etching technology to improve product quality and performance.

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